Tungsten-based nanocatalysts with different structures for visible light responsive photocatalytic degradation of bisphenol A.

Environmental pollution, such as water contamination, is a critical issue that must be absolutely addressed. Here, three different morphologies of tungsten-based photocatalysts (WO3 nanorods, WO3/WS2 nanobricks, WO3/WS2 nanorods) are made using a simple hydrothermal method by changing the solvents (H2O, DMF, aqueous HCl solution). The as-prepared nanocatalysts have excellent thermal stability, large porosity, and high hydrophilicity. The results show all materials have good photocatalytic activity in aqueous media, with WO3/WS2 nanorods (NRs) having the best activity in the photodegradation of bisphenol A (BPA) under visible-light irradiation. This may originate from increased migration of charge carriers and effective prevention of electron‒hole recombination in WO3/WS2 NRs, whereby this photocatalyst is able to generate more reactive •OH and •O2- species, leading to greater photocatalytic activity. About 99.6% of BPA is photodegraded within 60 min when using 1.5 g/L WO3/WS2 NRs and 5.0 mg/L BPA at pH 7.0. Additionally, the optimal conditions (pH, catalyst dosage, initial BPA concentration) for WO3/WS2 NRs are also elaborately investigated. These rod-like heterostructures are expressed as potential catalysts with excellent photostability, efficient reusability, and highly active effectivity in different types of water. In particular, the removal efficiency of BPA by WO3/WS2 NRs reduces by only 1.5% after five recycling runs and even reaches 89.1% in contaminated lake water. This study provides promising insights for the nearly complete removal of BPA from wastewater or different water resources, which is advantageous to various applications in environmental remediation.

Correction: Highly efficient degradation of reactive black KN-B dye by ultraviolet light responsive ZIF-8 photocatalysts with different morphologies.

[This corrects the article DOI: 10.1039/D2RA08312D.].

Application Prospects of MXenes Materials Modifications for Sensors.

The first two-dimensional (2D) substance sparked a boom in research since this type of material showed potential promise for applications in field sensors. A class of 2D transition metal nitrides, carbides, and carbonitrides are referred to as MXenes. Following the 2011 synthesis of Ti3C2 from Ti3AlC2, much research has been published. Since these materials have several advantages over conventional 2D materials, they have been extensively researched, synthesized, and studied by many research organizations. To give readers a general understanding of these well-liked materials, this review examines the structures of MXenes, discusses various synthesis procedures, and analyzes physicochemistry properties, particularly optical, electronic, structural, and mechanical properties. The focus of this review is the analysis of modern advancements in the development of MXene-based sensors, including electrochemical sensors, gas sensors, biosensors, optical sensors, and wearable sensors. Finally, the opportunities and challenges for further study on the creation of MXenes-based sensors are discussed.

Highly efficient degradation of reactive black KN-B dye by ultraviolet light responsive ZIF-8 photocatalysts with different morphologies.

Zeolitic imidazolate framework ZIF-8, a type of metal-organic framework, has diverse applications in multiple catalytic fields due to its outstanding properties. Herein, ZIF-8 photocatalysts with three different morphologies (dodecahedral, pitaya-like, and leaf-like) are successfully synthesized under ambient conditions from zinc salts by altering the volume ratio of methanol and water used as a solvent. The as-synthesized ZIFs have high crystallinity with distinct BET surface areas. The experiments indicate that the ZIFs have high photocatalytic efficiency, in which the leaf-like structure (ZIF-8-F3) is the most efficient in the degradation of reactive black KN-B dye (RB5) under 365 nm UV irradiation. This is due to the efficient inhibition of electron-hole recombination or the higher migration of charge carriers in ZIF-8-F3, thus producing more reactive oxygen species, resulting in greater photocatalytic efficiency. At pH = 11, more than 95% of RB5 is degraded within 2 hours when using 1.0 g L-1 of ZIF-8-F3. Besides, the photocatalytic and kinetic performances of ZIF-8-F3 are also investigated by optimizing the pH, initial RB5 concentration, and dosage of the used catalyst. These ZIF-8-F3 plates have been shown to be a promising material with high photostability and effective reusability, beneficial to various potential applications in environmental remediation issues.